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Organic conjugated polymers and polymer dots as photocatalysts for hydrogen production

《能源前沿（英文）》 2021年 第15卷 第1期   页码 667-677 doi: 10.1007/s11708-021-0767-7

摘要： Owing to the outstanding characteristics of tailorable electronic and optical properties, semiconducting polymers have attracted considerable attention in recent years. Among them, organic polymer dots process large breadth of potential synthetic diversity are the representative of photocatalysts for hydrogen production, which presents both an opportunity and a challenge. In this mini-review, first, the organic polymer photocatalysts were introduced. Then, recent reports on polymer dots which showed a superior photocatalytic activity and a robust stability under visible-light irradiation, for hydrogen production were summarized. Finally, challenges and outlook on using organic polymer dots-based photocatalysts from hydrogen production were discussed.

关键词： polymer dots (Pdots)     photocatalysis     hydrogen production    

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Enhanced charge extraction for all-inorganic perovskite solar cells by graphene oxide quantum dots modified

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 516-524 doi: 10.1007/s11705-022-2238-z

摘要： All-inorganic cesium lead bromide (CsPbBr3) perovskite solar cells have been attracting growing interest due to superior performance stability and low cost. However, low light absorbance and large charge recombination at TiO2/CsPbBr3 interface or within CsPbBr3 film still prevent further performance improvement. Herein, we report devices with high power conversion efficiency (9.16%) by introducing graphene oxide quantum dots (GOQDs) between TiO2 and perovskite layers. The recombination of interfacial radiation can be effectively restrained due to enhanced charge transfer capability. GOQDs with C-rich active sites can involve in crystallization and fill within the CsPbBr3 perovskite film as functional semiconductor additives. This work provides a promising strategy to optimize the crystallization process and boost charge extraction at the surface/interface optoelectronic properties of perovskites for high efficient and low-cost solar cells.

关键词： all inorganic     perovskite solar cells     graphene oxide quantum dots     high performance     stability    

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Carbon dots-based fluorescence sensor for two-photon imaging of pH in diabetic mice

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 298-306 doi: 10.1007/s11705-022-2212-9

摘要： Herein, a reversible pH fluorescent sensor was developed using caffeic acid as the precursor by one-step solvothermal synthesis method. The carbon dots-based sensor (CA-CDs) exhibited pH-dependent increase in fluorescence intensity and showed linear relationship in the range of pH 6.60 and 8.00. Notably, the fluorescence sensor has a reversible response to pH change. Finally, the CA-CDs has been successfully applied for two-photon imaging of the pH in liver and kidney of diabetic mice. Imaging results showed that the pH value in kidney of diabetic mice was lower than that of the normal mice, while the pH value in liver of diabetic mice was almost the same as that of the normal mice. The present study provides a simple analytical method for pH detection suitable for in vivo.

关键词： carbon dots     two-photon imaging     pH     diabetic mice    

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Improving hole transfer of boron nitride quantum dots modified PDI for efficient photodegradation

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1718-1727 doi: 10.1007/s11705-023-2319-7

摘要： In recent years, organic photocatalyst under visible-light absorption has shown significant potential for solving environmental problems. However, it is still a great challenge for constructing a highly active organic photocatalyst due to the low separation efficiency of photogenerated carriers. Herein, an effective and robust photocatalyst perylene-3,4,9,10-tetracarboxylic diamide/boron nitride quantum dots (PDI/BNQDs), consisting of self-assemble PDI with π–π stacking structure and BNQDs, has been constructed and researched under visible light irradiation. The PDI/BNQDs composite gradually increases organic pollutant photodegradation with the loading amount of BNQDs. With 10 mL of BNQDs solution added (PDI/BNQDs-10), the organic pollutant photodegradation performance reaches a maximum, about 6.16 times higher with methylene blue and 1.68 times higher with ciprofloxacin than that of pure PDI supramolecular. The enhancement is attributed to improved separation of photogenerated carriers from self-assembled PDI by BNQDs due to their preeminent ability to extract holes. This work is significant for the supplement of PDI supramolecular composite materials. We believe that this photocatalytic design is capable of expanding organic semiconductors’ potential for their applications in photocatalysis.

关键词： PDI     boron nitride     quantum dots     photocatalysis     hole transfer    

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Lignin-derived dual-function red light carbon dots for hypochlorite detection and anti-counterfeiting

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 966-975 doi: 10.1007/s11705-022-2244-1

摘要： The efficient utilization of natural lignin, which is the main by-product of the cellulose industry, is crucial for enhancing its economic value, alleviating the environmental burden, and improving ecological security. By taking advantage of the large sp2 hybrid domain of lignin and introducing amino functional groups, new lignin-derived carbon dots (SPN-CDs) with red fluorescence were successfully synthesized. Compared with green and blue fluorescent materials, red SPN-CDs have desirable anti-interference properties of short-wave background and exhibit superior luminescence stability. The SPN-CDs obtained exhibited sensitive and distinctive visible color with fluorescence-dual responses toward hypochlorite. Considering this feature, a portable, low-cost, and sensitive fluorescence sensing paper with a low limit of detection of 0.249 μmol∙L–1 was fabricated using the SPN-CDs for hypochlorite detection. Furthermore, a new type of visible-light and fluorescence dual-channel information encryption platform was constructed. Low-concentration hypochlorite can be employed as an accessible and efficient information encryption/decryption stimulus, as well as an information “eraser”, facilitating a safe and diversified transmission and convenient decryption of information. This work opens new avenues for high-value-added applications of lignin-based fluorescent materials.

关键词： alkali lignin     red light carbon dots     hypochlorite     encryption and anti-counterfeiting    

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Design and mechanism insight on SiC quantum dots sensitized inverse opal TiO with superior photocatalytic

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1913-1924 doi: 10.1007/s11705-023-2350-8

摘要： The combination of SiC quantum dots sensitized inverse opal TiO2 photocatalyst is designed in this work and then applied in wastewater purification under simulated sunlight. From various spectroscopic techniques, it is found that electrons transfer directionally from SiC quantum dots to inverse opal TiO2, and the energy difference between their conduction/valence bands can reduce the recombination rate of photogenerated carriers and provide a pathway with low interfacial resistance for charge transfer inside the composite. As a result, a typical type-II mechanism is proved to dominate the photoinduced charge transfer process. Meanwhile, the composite achieves excellent photocatalytic performances (the highest apparent kinetic constant of 0.037 min–1), which is 6.2 times (0.006 min–1) and 2.1 times (0.018 min–1) of the bare inverse opal TiO2 and commercial P25 photocatalysts. Therefore, the stability and non-toxicity of SiC quantum dots sensitized inverse opal TiO2 composite enables it with great potential in practical photocatalytic applications.

关键词： inverse opal TiO2     silicon carbide quantum dots     quantum dot sensitized photocatalyst     type-II charge transfer route    

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Glyco-functionalised quantum dots and their progress in cancer diagnosis and treatment

Jayshree Ashree, Qi Wang, Yimin Chao

《化学科学与工程前沿（英文）》 2020年 第14卷 第3期   页码 365-377 doi: 10.1007/s11705-019-1863-7

摘要： Despite all major breakthroughs in recent years of research, we are still unsuccessful to effectively diagnose and treat cancer that has express and metastasizes. Thus, the development of a novel approach for cancer detection and treatment is crucial. Recent progress in Glyconanotechnology has allowed the use of glycans and lectins as bio-functional molecules for many biological and biomedical applications. With the known advantages of quantum dots (QDs) and versatility of carbohydrates and lectins, Glyco-functionalised QD is a new prospect in constructing biomedical imaging platform for cancer behaviour study as well as treatment. In this review, we aim to describe the current utilisation of Glyco-functionalised QDs as well as their future prospective to interpret and confront cancer.

关键词： carbohydrate     leptin     glyco-functionalised QD     bioimaging     cancer diagnosis and treatment    

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Simplistic hydrothermal synthesis approach for fabricating photoluminescent carbon dots and its potential

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 536-547 doi: 10.1007/s11705-022-2239-y

摘要： The past decade has witnessed a variety of members of the carbon family along with exposure of carbon dots due to their magnificent properties in sensing, bioimaging, catalytic applications, biomedical fields, and so on. Herein, we report the simple hydrothermal method to fabricate photoluminescent doped carbon quantum dots for the detection of noxious lead(II) ions. Lead(II) ion is very venomous for both the environment and human health for which its detection is demanded area in the research field. The as-prepared carbon dots show excellent photostability, low toxicity and significant photoluminescence properties along with good water solubility. Along with these properties, carbon dots have a quantum yield of approximately 15%. In the practical field of application, these carbon dots have been used as sensing probes for the detection of lead(II) ions with a detection limit of 60 nmol·L–1. The fluorescence intensity of carbon dots was remarkably quenched in the presence of the lead(II) ion selectively among all the tested metal ions. Furthermore, we have studied the Stern–Volmer relationship for lead(II) quenching along with the explanation of the probable quenching mechanism. Ability of the doped carbon dots in heavy metal ions sensing in an environmental sample was demonstrated.

关键词： carbon dots     fluorescence     heavy metal sensing     practical application     photoluminescence    

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Enhanced permeability and biofouling mitigation of forward osmosis membranes via grafting graphene quantum dots

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1470-1483 doi: 10.1007/s11705-023-2329-5

摘要： In this paper, graphene oxide quantum dots with amino groups (NH2-GOQDs) were tailored to the surface of a thin-film composite (TFC) membrane surface for optimizing forward osmosis (FO) membrane performance using the amide coupling reaction. The results jointly demonstrated hydrophilicity and surface roughness of the membrane enhanced after grafting NH2-GOQDs, leading to the optimized affinity and the contact area between the membrane and water molecules. Therefore, grafting of the membrane with a concentration of 100 ppm (TFC-100) exhibited excellent permeability performance (58.32 L·m–2·h–1) compared with TFC membrane (16.94 L·m–2·h–1). In the evaluation of static antibacterial properties of membranes, TFC-100 membrane destroyed the cell morphology of Escherichia coli (E. coli) and reduced the degree of bacterial adsorption. In the dynamic biofouling experiment, TFC-100 membrane showed a lower flux decline than TFC membrane. After the physical cleaning, the flux of TFC-100 membrane could recover to 96% of the initial flux, which was notably better than that of TFC membrane (63%). Additionally, the extended Derjaguin–Landau–Verwey–Overbeek analysis of the affinity between pollutants and membrane surface verified that NH2-GOQDs alleviates E. coli contamination of membrane. This work highlights the potential applications of NH2-GOQDs for optimizing permeability and biofouling mitigation of FO membranes.

关键词： forward osmosis membrane     graphene oxide quantum dots     graft modification     anti-fouling membrane     XDLVO theory    

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combination of photothermal and chemodynamic therapy functions of CuS cores with red emitting carbon dots

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2144-2155 doi: 10.1007/s11705-023-2362-4

摘要： This study introduces multifunctional silica nanoparticles that exhibit both high photothermal and chemodynamic therapeutic activities, in addition to luminescence. The activity of the silica nanoparticles is derived from their plasmonic properties, which are a result of infusing the silica nanoparticles with multiple Cu2–xS cores. This infusion process is facilitated by a recoating of the silica nanoparticles with a cationic surfactant. The key factors that enable the internal incorporation of the Cu2–xS cores and the external deposition of red-emitting carbon dots are identified. The Cu2–xS cores within the silica nanoparticles exhibit both self-boosting generation of reactive oxygen species and high photothermal conversion efficacy, which are essential for photothermal and chemodynamic activities. The silica nanoparticles’ small size (no more than 70 nm) and high colloidal stability are prerequisites for their cell internalization. The internalization of the red-emitting silica nanoparticles within cells is visualized using fluorescence microscopy techniques. The chemodynamic activity of the silica nanoparticles is associated with their dark cytotoxicity, and the mechanisms of cell death are evaluated using an apoptotic assay. The photothermal activity of the silica nanoparticles is demonstrated by significant cell death under near-infrared (1064 nm) irradiation.

关键词： copper sulfide nanoparticles     chemodynamic therapy     photothermal therapy     carbon dots     silica nanoparticles    

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Construction of interfacial dynamic bonds for high performance lignin/polymer biocomposites

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1372-1388 doi: 10.1007/s11705-023-2302-3

摘要： Lignin is the largest natural aromatic biopolymer, but usually treated as industrial biomass waste. The development of lignin/polymer biocomposites can promote the high value utilization of lignin and the greening of polymers. However, the weak interfacial interaction between industrial lignin and polymer induces poor compatibility and serious agglomeration in polymer owing to the strong intermolecular force of lignin. As such, it is extremely difficult to prepare high performance lignin/polymer biocomposites. Recently, we proposed the strategy of in situ construction of interfacial dynamic bonds in lignin/polymer composites. By taking advantage of the abundant oxygen-containing polar groups of lignin, we inserted dynamic bonding connection such as hydrogen bonds and coordination bonds into the interphase between lignin and the polymer matrix to improve the interfacial interactions. Meanwhile, the natural amphiphilic structure characteristics of lignin were utilized to construct the hierarchical nanophase separation structure in lignin/polymer composites. The persistent problems of poor dispersity and interfacial compatibility of lignin in the polymer matrix were effectively solved. The lignin-modified polymer composites achieved simultaneously enhanced strength and toughness. This concise review systematically summarized the recent research progress of our group toward building high-performance lignin/polymer biocomposites through the design of interfacial dynamic bonds (hydrogen bonds, coordination bonds, and dynamic covalent bonds) between lignin and different polymer systems (polar plastics, rubber, polyurethane, hydrogels, and other polymers). Finally, the future development direction, main challenges, and potential solutions of lignin application in polymers were presented.

关键词： lignin     polymer     interfacial dynamic bonds    

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Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 265-268 doi: 10.1007/s11705-008-0054-8

摘要： The polymer stabilized liquid crystal (PSLC) film is a relatively novel electro-optical material, which is generally obtained by dissolving a small amount of a bifunctional photoreactive monomer in a low molecular mass liquid crystal. In this paper, the PSLC films were prepared with photoreactive biphenyl methacrylate monomers by photopolymerization induced phase separation. The effects of liquid crystal concentration, curing time, monomer structures and alignment layer on the electro-optical properties of PSLC films were investigated. The results show that the transmittance in the OFF state () increased with the liquid crystal concentration, but the driving voltage decreased. was also influenced by the curing time. Furthermore, when polyimide was used as alignment layer, the films prepared from the bifunctional monomer shows a higher T, while those from the single functional monomer exhibited a deformed electro-optical curve due to the unsteady polymer networks.
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Deformation analysis of shape memory polymer for morphing wing skin under airflow

Weilong YIN, Jingcang LIU, Jinsong LENG,

《机械工程前沿（英文）》 2009年 第4卷 第4期   页码 447-449 doi: 10.1007/s11465-009-0062-5

摘要： The method for analyzing the out-of-plane deformation of a flexible skin under airflow is developed in this paper. The aerodynamic analysis is performed using the CFD software, and the structural analysis is performed using finite element method. The chief aim of the present study is to investigate the out-of-plane deformation of the shape memory polymer (SMP) skin at different temperatures. Numerical results show that the maximum out-of-plane displacement of the SMP skin increases with increasing temperature. When the SMP skin is heated to 53°C, the maximum out-of-plane displacement is about 7 mm. It decreases by 72%, when the SMP skin is applied with a uniform pre-strain of 0.1.

关键词： aircraft     morphing     skin     shape memory polymer (SMP)     deformation     pre-strain    

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Fracture model for the prediction of the electrical percolation threshold in CNTs/Polymer composites

Yang SHEN, Pengfei HE, Xiaoying ZHUANG

《结构与土木工程前沿（英文）》 2018年 第12卷 第1期   页码 125-136 doi: 10.1007/s11709-017-0396-8

摘要： In this paper, we propose a 3D stochastic model to predict the percolation threshold and the effective electric conductivity of CNTs/Polymer composites. We consider the tunneling effect in our model so that the unrealistic interpenetration can be avoided in the identification of the conductive paths between the CNTs inside the polymer. The results are shown to be in good agreement with reported experimental data.

关键词： electrical percolation     CNTs/Polymer composites     fracture model     electric conductivity     tunnelling effects    

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Experimental investigation on freeze−thaw durability of polymer concrete

《结构与土木工程前沿（英文）》 2021年 第15卷 第4期   页码 1038-1046 doi: 10.1007/s11709-021-0748-2

摘要： Assessing the durability of concrete is of prime importance to provide an adequate service life and reduce the repairing cost of structures. Freeze–thaw is one such test that indicates the ability of concrete to last a long time without a significant loss in its performance. In this study, the freeze–thaw resistance of polymer concrete containing different polymer contents was explored and compared to various conventional cement concretes. Concretes’ fresh and hardened properties were assessed for their workability, air content, and compressive strength. The mass loss, length change, dynamic modulus of elasticity, and residual compressive strength were determined for all types of concretes subjected to freeze–thaw cycles according to ASTM C666-procedure A. Results showed that polymer concrete (PC) specimens prepared with higher dosages of polymer contents possessed better freeze–thaw durability compared to other specimens. This high durability performance of PCs is mainly due to their impermeable microstructures, absence of water in their structure, and the high bond strength between aggregates and a polymer binder. It is also indicated that the performance of high-strength concrete containing air-entraining admixture is comparable with PC having optimum polymer content in terms of residual compressive strength, dynamic modulus of elasticity, mass loss, and length change.

关键词： durability test     freeze-thaw resistance     polymer concrete     residual compressive strength     ASTM C666-15    

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标题 作者 时间 类型 操作

Organic conjugated polymers and polymer dots as photocatalysts for hydrogen production

期刊论文

Enhanced charge extraction for all-inorganic perovskite solar cells by graphene oxide quantum dots modified

期刊论文

Carbon dots-based fluorescence sensor for two-photon imaging of pH in diabetic mice

期刊论文

Improving hole transfer of boron nitride quantum dots modified PDI for efficient photodegradation

期刊论文

Lignin-derived dual-function red light carbon dots for hypochlorite detection and anti-counterfeiting

期刊论文

Design and mechanism insight on SiC quantum dots sensitized inverse opal TiO with superior photocatalytic

期刊论文

Glyco-functionalised quantum dots and their progress in cancer diagnosis and treatment

Jayshree Ashree, Qi Wang, Yimin Chao

期刊论文

Simplistic hydrothermal synthesis approach for fabricating photoluminescent carbon dots and its potential

期刊论文

Enhanced permeability and biofouling mitigation of forward osmosis membranes via grafting graphene quantum dots

期刊论文

combination of photothermal and chemodynamic therapy functions of CuS cores with red emitting carbon dots

期刊论文

Construction of interfacial dynamic bonds for high performance lignin/polymer biocomposites

期刊论文

Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

期刊论文

Deformation analysis of shape memory polymer for morphing wing skin under airflow

Weilong YIN, Jingcang LIU, Jinsong LENG,

期刊论文

Fracture model for the prediction of the electrical percolation threshold in CNTs/Polymer composites

Yang SHEN, Pengfei HE, Xiaoying ZHUANG

期刊论文

Experimental investigation on freeze−thaw durability of polymer concrete

期刊论文